Monofunctionalized pillar[5]arenes: synthesis and supramolecular structure.

نویسندگان

  • Tomoki Ogoshi
  • Kazuki Demachi
  • Keisuke Kitajima
  • Tada-Aki Yamagishi
چکیده

The first synthesis of a monohydroxy pillar[5]arene has been carried out, by controlling the de-O-methylation of per-methylated pillar[5]arene. Using monohydroxy pillar[5]arene as an intermediate, mono-guest-functionalized pillar[5]arene was prepared. It formed a self-inclusion complex in CDCl(3) whereas in acetone-d(6) dethreading of the guest moiety took place.

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عنوان ژورنال:
  • Chemical communications

دوره 47 25  شماره 

صفحات  -

تاریخ انتشار 2011